Morpholine contains secondary amine groups and has all the typical reactive characteristics of secondary amine groups. It can react with inorganic acids to form salts, and react with organic acids to form salts or amides, which can be subjected to alkylation reaction, and can also be reacted with ethylene oxide, ketone or Willgerodt reaction. Morpholine is a six-membered ring containing oxygen and nitrogen, and its alkalinity is much lower than that of its parent piperidine. The marketed morpholine drugs are mainly distributed in the fields of tumors, cardiovascular and cerebrovascular diseases, respiratory system diseases, digestive system diseases, infectious diseases and mental disorders.
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Cinnoline is a heterocyclic binuclear base containing two vicinal nitrogen atoms. Over the past two centuries, fused N-heterocyclic compounds have been widely used as valuable entities for expanding pharmacologically important reagents and have been recognized as an advantageous scaffold. Among the numerous fused N-heterocyclic compounds, cinnoline, quinoxaline, and quinazoline are important pharmacological agents, and a great deal of research has been done on this class of compounds. In medicinal chemistry, these N-heterocyclic compounds have a wide range of biological properties and can be used as synthetic intermediates, potential drug candidates and chemical probes.
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